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Optical Micro-Characterization of Single-Walled
Carbon Nanotubes Extracted from AFI Crystals by Visible Emission and
Raman Scattering. Jian-Ting YE, Nobuko NAKA, Yasushi MORIHIRA, Zi-Kang
TANG, Wei-kun GE, Ping SHENG, Igor KUDRYASHOV, and Nobukata NAGASAWA:
Japanese Journal of Allied Physics, Vol. 43, No. 10, 2004, pp.
7354-7355.
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Optical Nano-Tomography on Photosensitive
Single-Wall Carbon Nanotube Arrays in Zeolite Crystals.
Nobukata NAGASAWA, Hirokazu SUGIYAMA, Nobuko NAKA, Igor KUDRYASHOV,
Zhao-Ming LI and Zi-Kang TANG: Japanese Journal of Applied Physics, Vol.
43, No. 2, 2004, pp. 868-871.
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Optical
Micro-Characterization of Single-Walled Carbon Nanotubes Extracted from
AFI Crystals by Visible Emission and Raman Scattering. Jian-Ting
YE, Nobuko NAKA, Yasushi MORIHIRA, Zi-Kang TANG, Wei-kun GE, Ping SHENG,
Igor KUDRYASHOV, and Nobukata NAGASAWA: Japanese Journal of Applied
Physics, Vol. 43, No. 10, 2004, pp. 7354-7355.
N.
Nagasawa, H. Sugiyama, N.Naka, I. Kudryashov, M. Watanabe, T. Hayashi,
I. Bozovic, N. Bozovic, G. Li, Z. Li, Z.K. Tang
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Visible
emission of single wall carbon nanotubes formed in micro-channels of
zeolite crystals N. Nagasawa, H.
Sugiyama, N. Naka, I. Kudryashov, M. Watanabe, T. Hayashi, I. Bozovic,
N. Bosovic, G. Li, Z.K. Tang.
Abstract:
Emission spectroscopy is performed to study the optical transitions
between electronic bands of SWCNs formed in AlPO4-5 (AFI )crystal.
Strong visible emission is observed under laser light illumination at
room temperature. The emission is excited by the light polarized along
the c- axis and its polarization is also along this direction. On the
other hand, non-linear emission is observed under the resonant
excitation of the lowest absorption band of SWCNs. The emission is
excited by the light polarized along the c—axis, but it shows the
polarization perpendicular to the c—axis. The polarization character is
discussed on the basis of the selection rules of the optical transitions
predicted by the full line-group symmetry of SWCNs.
(c)2002 Elsevier Science B.V. All rights reserved.
PACS: 78.67.Ch;81.07.De
Keywords: Carbon nanotubes;Zeolite;Optical absorption;Optical
non-linearity
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Optical Nano-Tomography on Photosensitive
Single-Wall Carbon Nanotube Arrays in Zeolite Crystals.
Nobukata NAGASAWA, Hirokazu SUGIYAMA, Nobuko NAKA, Igor KUDRYASHOV,
Zhao-Ming LI and Zi-Kang TANG: Japanese Journal of Allied Physics, Vol.
43, No. 2, 2004, pp. 868-871.
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Three-dimensional mapping of Photoluminescence and
Raman Spectra. I. Kudryashov, A. Gvozdev, V. Zhihimontov, A.
Volkov, E. Vanagas, S. Juodkazis, H. Misawa.
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Visible Emissions of Single-Walled Carbon Nanotubes
Formed in Zeolite Crystals. N. Nagasawa,
I. Kudryashov, and Z. K. Tang
Abstract: Mono-sized, aligned and single-walled carbon nanotubes (SWCNs)
of about 0.4 nm diameter are formed inside micro-channel array of a
zeolite single crystal. Since they are forced to align along c-axis of
the crystal, they show strong polarization anisotropy in the optical
absorption from near infrared to visible region [1]. The crystal is
opaque in the polarization configuration E//c , but is almost
transparent in E?c , where E is the electric field vector of the
incident light. We have found strong emissions in visible regions under
the monochromatic photo-excitations at room temperature. They showed
strong polarization correlation with the absorption spectra. To know the
spatial distribution of the emission sources and the origins, 3D micro-tomographic
measurements are performed using the "Nanofinder" of nano-scale spatial
resolution [2]. In this paper, we discuss these polarization
characteristics in view of the selection rules of relevant optical
transitions on the basis of the band calculation obtained by the LDA.
[1] Z.K.Tang, Z.M.Li, G.D.Li, N.Wang, H.J.Li and C.T.Chan, to be
published in the Proceedings of Inter. Symposium on Network Materials:
Fullerenes, Nanotubes, and Related Systems, ISNM2001, Kamakura, Japan.
[2] N.Nagasawa, I.Kudryashov, S.Tsuda, and Z.K.Tang, to be published in
the Proceedings of ISNM2001
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Heteroepitaxial growth of wurtzite InN films on
Si.111. exhibiting strong near-infrared photoluminescence at room
temperature S. Gwo, C.-L. Wu, and C.-H.
Shen W.-H. Chang and T. M.
Hsu(Received 1 December 2003; accepted 10 March 2004; published online
29 April 2004) Abstract: High-quality InN epitaxial films have been
grown by nitrogen-plasma-assisted molecular-beam epitaxy on Si(111)
substrates using a double-buffer technique. Growth of a (0001)
-oriented single crystalline wurtzite–InN layer was confirmed by
reflection high-energy electron diffraction, x-ray diffraction, and
Raman scattering. At room temperature, these films exhibited strong
near-infrared ~0.6–0.9 eV! photoluminescence (PL). In addition to the
optical absorption measurement of absorption edge and direct band
nature, the PL signal was found to depend linearly on the excitation
laser intensity over a wide intensity range. These results indicate that
the observed PL is due to the emission of direct band-to-band
recombination rather than the band-to-defect (or impurity) deep
emission. © 2004 American Institute of Physics. @DOI: 10.1063/1.1738183
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